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Influence of Alkali Metal Substitution on the Phase Transition Behavior of CsGaQ2 (Q = S, Se)

Friedrich, Daniel , Schlosser, Marc, Etter, Martin and Pfitzner, Arno (2017) Influence of Alkali Metal Substitution on the Phase Transition Behavior of CsGaQ2 (Q = S, Se). Crystals 7, p. 379.

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Abstract

The formation of solid solution series Cs(1-x)M(x)GaQ(2)-mC64 (M = K, Rb; Q = S, Se; x = 0-1) was studied by X-ray diffraction and spectroscopic methods, revealing a complete miscibility of CsGaQ(2)-mC64 with RbGaQ(2) and KGaSe2, and a large miscibility gap with KGaS2. All solid solution members exhibit similar Raman spectra, indicating the covalent Ga-Q bonding character. The similar optical ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner
Identification Number:
ValueType
10.3390/cryst7120379DOI
Keywords:CRYSTAL-STRUCTURE; STRUCTURAL-CHARACTERIZATION; PHYSICAL-PROPERTIES; GALLIUM; KINETICS; KFES2; chalcogenogallates; polymorphism; solid solutions; in situ X-ray diffraction; synchrotron radiation; Rietveld refinement
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:37622
Owner only: item control page

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