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Unprecedented Mechanism of an Organocatalytic Route to Conjugated Enynes with a Junction to Cyclic Nitronates

Streitferdt, Verena, Haindl, Michael Holger, Hioe, Johnny, Morana, Fabio, Renzi, Polyssena, von Rekowski, Felicitas, Zimmermann, Alexander, Nardi, Martina, Zeitler, Kirsten and Gschwind, Ruth M. (2019) Unprecedented Mechanism of an Organocatalytic Route to Conjugated Enynes with a Junction to Cyclic Nitronates. European Journal of Organic Chemistry 2019 (2019), pp. 328-337.

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Other URL: http://doi.org/10.1002/ejoc.201801153


Abstract

Conjugated enynes as well as cyclic nitronates are crucial building blocks for numerous natural products and pharmaceuticals. However, so far, no common and metal‐free synthetic route to both conjugated enynes and cyclic nitronates has been reported. Here, in situ NMR, labelling studies and theoretical calculations were combined to investigate the mechanism of the unusual triple bond formation ...

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Item type:Article
Date:2019
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1002/ejoc.201801153DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:37780
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