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1,10-Phenanthroline-dithiine iridium and ruthenium complexes: synthesis, characterization and photocatalytic dihydrogen evolution

Erdmann, Elisa ; Villinger, A. ; König, Burkhard ; Seidel, W. W.



Abstract

We report the synthesis and the spectroscopic and electrochemical properties of six mononuclear iridium(III) and ruthenium(II) complexes bearing S,S′-extended phenanthroline ligands. Starting from 5,6-dibromide-1,10-phenanthroline, the dithiine derivatives N,N′-1,10-phenanthrolinedithiino[2,3-b]quinoxaline and N,N′-1,10-phenanthrolinedithiino[2,3-b]benzene were prepared by primary ...

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