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Hydration and ion association of La3+ and Eu3+ salts in aqueous solution

Friesen, Sergej ; Krickl, Sebastian ; Luger, M. ; Nazet, Andreas ; Hefter, Glenn ; Buchner, Richard


Aq. solns. of five lanthanide salts: LaCl3, La(NO3)3, La2(SO4)3, Eu(NO3)3 and Eu2(SO4)3 were studied at 25° by dielec. relaxation spectroscopy over the frequency range 0.05 ≤ ν/GHz ≤ 89. Detailed anal. of the solvent-related modes located at higher frequencies showed that both La3+ and Eu3+ are strongly hydrated, even including partial formation of a third hydration shell similar to that ...


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