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Hydration and ion association of La3+ and Eu3+ salts in aqueous solution

Friesen, Sergej, Krickl, Sebastian, Luger, M., Nazet, Andreas, Hefter, Glenn and Buchner, Richard (2018) Hydration and ion association of La3+ and Eu3+ salts in aqueous solution. Physical Chemistry Chemical Physics 20 (13), pp. 8812-8821.

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Abstract

Aq. solns. of five lanthanide salts: LaCl3, La(NO3)3, La2(SO4)3, Eu(NO3)3 and Eu2(SO4)3 were studied at 25° by dielec. relaxation spectroscopy over the frequency range 0.05 ≤ ν/GHz ≤ 89. Detailed anal. of the solvent-related modes located at higher frequencies showed that both La3+ and Eu3+ are strongly hydrated, even including partial formation of a third hydration shell similar to that ...

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Item type:Article
Date:2018
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1039/C8CP00248GDOI
Keywords:hydration ion lanthanum europium salt aq soln
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:37997
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