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The Interplay of Methyl-Group Distribution and Hydration Pattern of Isomeric Amphiphilic Osmolytes

Agieienko, Vira ; Hölzl, C. ; Horinek, Dominik ; Buchner, Richard


The intermol. interactions and dynamics of aq. 1,​1-​dimethyurea (1,​1-​DMU) solns. were studied by examg. the concn. dependence of the solvent and solute relaxations detected by dielec. spectroscopy. Mol. dynamics simulations were carried out to facilitate interpretation of the dielec. data and to get a deeper insight into the behavior of the system components at the microscopic level. In ...


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