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The Interplay of Methyl-Group Distribution and Hydration Pattern of Isomeric Amphiphilic Osmolytes

Agieienko, Vira, Hölzl, C., Horinek, Dominik and Buchner, Richard (2018) The Interplay of Methyl-Group Distribution and Hydration Pattern of Isomeric Amphiphilic Osmolytes. Journal of Physical Chemistry B 122 (22), pp. 5972-5983.

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Abstract

The intermol. interactions and dynamics of aq. 1,​1-​dimethyurea (1,​1-​DMU) solns. were studied by examg. the concn. dependence of the solvent and solute relaxations detected by dielec. spectroscopy. Mol. dynamics simulations were carried out to facilitate interpretation of the dielec. data and to get a deeper insight into the behavior of the system components at the microscopic level. In ...

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Item type:Article
Date:2018
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1021/acs.jpcb.8b01699DOI
Keywords:methyurea soln hydrogen bond dielec relaxation
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:37999
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