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Ion fluctuations and intermembrane interactions in the aqueous dispersions of a dialkylchain cationic surfactant studied using dielectric relaxation spectroscopy and small- and wide-​angle X-​ray scattering

Yanase, K., Obikane, M., Ogura, T., Buchner, Richard , Igarashi, A. and Sato, T. (2018) Ion fluctuations and intermembrane interactions in the aqueous dispersions of a dialkylchain cationic surfactant studied using dielectric relaxation spectroscopy and small- and wide-​angle X-​ray scattering. Physical Chemistry Chemical Physics 20 (41), pp. 26621-26633.

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Abstract

A dialkylchain cationic surfactant forms the so-​called α-​gel in water showing virtually no fluidity, which is transformed into a highly fluidic dispersion upon addn. of a small amt. of salt. This intriguing phenomenon is utilized in household industries. However, the underlying mechanisms remain unclear. Here, we use dielec. relaxation spectroscopy (DRS) and simultaneous small- and ...

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Item type:Article
Date:2018
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1039/c8cp05575kDOI
Keywords:dialkylchain cationic surfactant dielec relaxation spectrum SWAXS
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38013
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