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Structural Characterization of MoOCl3(THF)2, the Pre-Reagent for Kauffmann Olefination Reactions

URN to cite this document:
urn:nbn:de:bvb:355-epub-381131
DOI to cite this document:
10.5283/epub.38113
Vitzthumecker, Christoph ; Robinson, Fred ; Pfitzner, Arno
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Date of publication of this fulltext: 10 Dec 2018 14:13


Abstract

Single crystals of molybdenum-oxy-di-tetrahydrouran-trichloride were obtained by the reaction of Mo2Cl10, tetrahydrofuran, sulfur, and P4S3 in carbon disulfide after layering the solution with n-hexane. Single crystal structure determination at T = 123 K reveals that MoOCl3(THF)(2) crystalizes in the orthorhombic space group P2(1)2(1)2(1) with the lattice constants a = 7.8620(9) angstrom, b = ...

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