Phosphorescent heterobimetallic complexes involving platinum(IV) and rhenium(VII) centers, connected by unsupported μ-oxido bridge

URN to cite this document:: urn:nbn:de:bvb:355-epub-381170
DOI to cite this document:: 10.5283/epub.38117

Molaee, H. ; Nabavizadeh, S. M.

; Jamshidi, M.

; Vilsmeier, Max ; Pfitzner, Arno

; Samandar Sangari, M.

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Date of publication of this fulltext: 11 Dec 2018 10:18

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Abstract

Heterobimetallic compounds [(C<^>N)LMe2Pt(mu-O)ReO3] (C<^>N = ppy, L = PPh3, 2a; C<^>N = ppy, L = PMePh2, 2b; C<^>N = bhq, L = PPh3, 2c; C<^>N = bhq, L = PMePh2, 2d) containing a discrete unsupported Pt(IV)-O-Re(VII) bridge have been synthesized through a targeted synthesis route. The compounds have been prepared by a single-pot synthesis in which the Pt(IV) precursor [PtMe2I(C<^>N)L] complexes ...