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Visible-light mediated C–C bond cleavage of 1,2-diols to carbonyls by cerium-photocatalysis

Schwarz, Johanna and König, Burkhard (2019) Visible-light mediated C–C bond cleavage of 1,2-diols to carbonyls by cerium-photocatalysis. Chemical Communications 55, pp. 486-488.

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Abstract

We describe a photocatalyticmethod for the cleavage of vicinal diols to aldehydes and ketones. The reaction is catalyzed by blue light and a cerium-catalyst and the scope includes aryl as well as alkyl substituted diols. The simple protocol which works under air and at room temperature enables the valorization of abundant diols.


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Item type:Article
Date:2019
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1039/c8cc09208gDOI
Keywords:photocatalysis; cerium-catalysts
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38156
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