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Si44-in Solution - First Solvate Crystal Structure of the Ligand-free Tetrasilicide Tetraanion in Rb1.2K2.8Si4·7NH3

Lorenz, Corinna, Gärtner, Stefanie and Korber, Nikolaus (2016) Si44-in Solution - First Solvate Crystal Structure of the Ligand-free Tetrasilicide Tetraanion in Rb1.2K2.8Si4·7NH3. Zeitschrift für anorganische und allgemeine Chemie 643 (2), pp. 141-145.

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Other URL: http://doi.org/10.1002/zaac.201600336


Abstract

We report the first solvate structure of the silicide anion Si-4(4-), which provides circumstantial evidence of the stability of the highly charged anion in liquid ammonia solutions. The solvate Rb(1.2)K(2.8)Si(4)7NH(3) crystallized from a mixture of the ternary compound K6Rb6Si17 with the transition metal complex [(C6H5)(3)P](2)Ni(CO)(2) [bis(triphenylphosphine)dicarbonylnickel] in the presence ...

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Item type:Article
Date:2016
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber
Identification Number:
ValueType
10.1002/zaac.201600336DOI
Keywords:ALKALIMETALLE ZU HALBMETALLEN; QUANTUM-MECHANICAL CALCULATIONS; LIQUID-AMMONIA; ZINTL CLUSTERS; DAS VERHALTEN; SOLUTION CHEMISTRY; ELEMENTS; ANIONS; REFINEMENT; RB; Silicon; X-ray diffration; Zintl anions; Liquid ammonia
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38515
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