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Click-binol-phosphoric acid catalysts in intramolecular enantioselective oxidative C H-bond functionalization

Stockerl, Sebastian, Gutiérrez, Daniel and García Mancheño, Olga (2017) Click-binol-phosphoric acid catalysts in intramolecular enantioselective oxidative C H-bond functionalization. Journal of Molecular Catalysis A: Chemical 426, pp. 572-585.

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Other URL: http://doi.org/10.1016/j.molcata.2016.09.006


Abstract

Counteranion-catalysis represents an appealing but challenging approach for the development of enantioselective oxidative C-H bond functionalization reactions. In this work, a new family of 3,3'-triazolyl BINOL-derived phosphoric acids was synthesized and employed in the intramolecular asymmetric C-H bond functionalization of N-aryl substituted tetrahydroisoquinolines. As previously reported with ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie
Identification Number:
ValueType
10.1016/j.molcata.2016.09.006DOI
Keywords:NITROGEN ATOM; TETRAHYDROISOQUINOLINE DERIVATIVES; ASYMMETRIC CATALYSIS; COUPLING REACTIONS; TERTIARY-AMINES; ALPHA-ARYLATION; BRONSTED ACID; ACTIVATION; ALDEHYDES; ORGANOCATALYSIS; C-H functionalization; Oxidation; Organocatalysis; Enantioselective; Heterocycles
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38550
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