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Alkene Hydrogenations by Soluble Iron Nanocluster Catalysts

Gieshoff, Tim N., Chakraborty, Uttam , Villa, Matteo and Jacobi von Wangelin, Axel (2017) Alkene Hydrogenations by Soluble Iron Nanocluster Catalysts. Angewandte Chemie International Edition 56 (13), pp. 3585-3589.

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Other URL: http://doi.org/10.1002/anie.201612548


Abstract

The replacement of noble metal technologies and the realization of new reactivities with earth-abundant metals is at the heart of sustainable synthesis. Alkene hydrogenations have so far been most effectively performed by noble metal catalysts. This study reports an iron-catalyzed hydrogenation protocol for tri- and tetra-substituted alkenes of unprecedented activity and scope under mild ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Axel Jacobi von Wangelin
Identification Number:
ValueType
10.1002/anie.201612548DOI
Keywords:H BOND AMINATION; HETEROGENEOUS CATALYSIS; COMPLEXES; OLEFINS; CLUSTER; FE; NANOPARTICLES; REDUCTION; ELECTRON; BEHAVIOR; amides; hydrides; hydrogenations; iron; nanoclusters
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38599
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