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Alkene Hydrogenations by Soluble Iron Nanocluster Catalysts

Gieshoff, Tim N. ; Chakraborty, Uttam ; Villa, Matteo ; Jacobi von Wangelin, Axel


The replacement of noble metal technologies and the realization of new reactivities with earth-abundant metals is at the heart of sustainable synthesis. Alkene hydrogenations have so far been most effectively performed by noble metal catalysts. This study reports an iron-catalyzed hydrogenation protocol for tri- and tetra-substituted alkenes of unprecedented activity and scope under mild ...


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