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Alkene Metalates as Hydrogenation Catalysts

Büschelberger, Philipp, Gärtner, Dominik, Reyes-Rodriguez, Efrain, Kreyenschmidt, Friedrich, Koszinowski, Konrad, Jacobi von Wangelin, Axel and Wolf, Robert (2017) Alkene Metalates as Hydrogenation Catalysts. Chemistry - A European Journal 23 (13), pp. 3139-3151.

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Other URL: http://doi.org/10.1002/chem.201605222


Abstract

First-row transition-metal complexes hold great potential as catalysts for hydrogenations and related reductive reactions. Homo-and heteroleptic arene/alkene metalates(1-) (M=Co, Fe) are a structurally distinct catalyst class with good activities in hydrogenations of alkenes and alkynes. The first syntheses of the heteroleptic cobaltates [K([18]crown-6)][Co(eta(4)-cod)(eta(2)-styrene)(2)] (5) and ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf
Identification Number:
ValueType
10.1002/chem.201605222DOI
Keywords:OLEFIN HYDROGENATION; TRANSITION-METALS; COBALT COMPLEXES; IRON CATALYSTS; HOMOGENEOUS HYDROGENATION; ASYMMETRIC HYDROGENATION; SELECTIVE HYDROGENATION; COUPLING REACTIONS; DIALKYL COMPLEXES; MASS-SPECTROMETRY; cobalt; hydrogenation; iron; reaction mechanisms; transition metals
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38623
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