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Dinuclear indium and thallium diyls: biscarbenoids or metal cluster?

Desat, Marcella E., Gärtner, Stefanie and Kretschmer, Robert (2017) Dinuclear indium and thallium diyls: biscarbenoids or metal cluster? Chemical Communications 53 (9), pp. 1510-1513.

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Other URL: http://doi.org/10.1039/c6cc09488k


Abstract

Using bis(beta-diketiminate) ligands we were able to synthesize unprecedented indium and thallium biscarbenoids. For indium, a novel four-membered metallacycle is derived from intra-and intermolecular In-In interactions in the solid state, while for thallium only an intramolecular Tl-2-pseudo-dimer is obtained. Computational studies revealed that the solid-state structures benefit significantly from dispersion stabilization.


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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Dr. Robert Kretschmer
Identification Number:
ValueType
10.1039/c6cc09488kDOI
Keywords:CARBENE ANALOG; STRUCTURAL-CHARACTERIZATION; BETA-DIKETIMINATO; LONDON DISPERSION; SOLID-STATE; COMPLEXES; COMPOUND; GALLIUM; CHEMISTRY; ELEMENTS;
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38793
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