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Electronic Structure and Magnetic Anisotropy of an Unsaturated Cyclopentadienyl Iron(I) Complex with 15 Valence Electrons

Chakraborty, Uttam , Demeshko, Serhiy, Meyer, Franc , Rebreyend, Christophe, de Bruin, Bas , Atanasov, Mihail, Neese, Frank , Mühldorf, Bernd and Wolf, Robert (2017) Electronic Structure and Magnetic Anisotropy of an Unsaturated Cyclopentadienyl Iron(I) Complex with 15 Valence Electrons. Angewandte Chemie International Edition 56 (27), pp. 7995-7999.

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Other URL: http://doi.org/10.1002/anie.201702454


Abstract

The 15 valence-electron iron(I) complex [(CpFe)-Fe-Ar-(IiPr(2)Me(2))] (1, Cp-Ar = C-5(C6H4-4-Et)(5); IiPr(2)Me(2) = 1,3-diiso-propyl-4,5-dimethylimidazolin-2-ylidene) was synthesized in high yield from the Fe-II precursor [(CpFe)-Fe-Ar(mu-Br)](2). Fe-57 Mossbauer and EPR spectroscopic data, magnetic measurements, and ab initio ligand-field calculations indicate an S=3/2 ground state with a large ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie
Identification Number:
ValueType
10.1002/anie.201702454DOI
Keywords:JAHN-TELLER DISTORTION; SINGLE-MOLECULE MAGNET; HIGH-SPIN IRON(II); AMMONIA-BORANE; LINEAR IRON(I); ROOM-TEMPERATURE; AMIDO COMPLEXES; DEHYDROGENATION; SPECTROSCOPY; RELAXATION; carbene ligands; cyclopentadienyl ligands; homogeneous catalysis; iron; magnetic properties
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38876
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