Kellner, Dominik, Weger, Maximilian, Gini, Andrea and Mancheño, Olga García (2017) Pd(OAc)2/Ph3P-catalyzed dimerization of isoprene and synthesis of monoterpenic heterocycles. Beilstein Journal of Organic Chemistry 13, pp. 1807-1815.
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Other URL: http://doi.org/10.3762/bjoc.13.175
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Abstract
The palladium-catalyzed dimerization of isoprene is a practical approach of synthesizing monoterpenes. Though several highly selective methods have been reported, most of them still required pressure or costly ligands for attaining the active system and desired selectivity. Herein, we present a simple and economical procedure towards the tail-to-tail dimer using readily available Pd(OAc)(2) and ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2017 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Olga Garcia Mancheño | ||||
| Identification Number: |
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| Keywords: | PALLADIUM-CATALYZED REACTIONS; (ETA-1,ETA-3-OCTADIENEDIYL)PALLADIUM COMPLEXES; CARBENE CATALYSTS; 1,3-DIENES; TELOMERIZATION; BUTADIENE; TETRAMERIZATION; OLIGOMERIZATION; NUCLEOPHILES; DERIVATIVES; dimerization; heterocycles; isoprene; monoterpene; palladium catalysis | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 39250 |
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