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Pd(OAc)2/Ph3P-catalyzed dimerization of isoprene and synthesis of monoterpenic heterocycles

Kellner, Dominik, Weger, Maximilian, Gini, Andrea and Mancheño, Olga García (2017) Pd(OAc)2/Ph3P-catalyzed dimerization of isoprene and synthesis of monoterpenic heterocycles. Beilstein Journal of Organic Chemistry 13, pp. 1807-1815.

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Other URL: http://doi.org/10.3762/bjoc.13.175

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Abstract

The palladium-catalyzed dimerization of isoprene is a practical approach of synthesizing monoterpenes. Though several highly selective methods have been reported, most of them still required pressure or costly ligands for attaining the active system and desired selectivity. Herein, we present a simple and economical procedure towards the tail-to-tail dimer using readily available Pd(OAc)(2) and ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Olga Garcia Mancheño
Identification Number:
ValueType
10.3762/bjoc.13.175DOI
Keywords:PALLADIUM-CATALYZED REACTIONS; (ETA-1,ETA-3-OCTADIENEDIYL)PALLADIUM COMPLEXES; CARBENE CATALYSTS; 1,3-DIENES; TELOMERIZATION; BUTADIENE; TETRAMERIZATION; OLIGOMERIZATION; NUCLEOPHILES; DERIVATIVES; dimerization; heterocycles; isoprene; monoterpene; palladium catalysis
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39250
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