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Evidence for cooperative Na+ and Cl− binding by strongly hydrated l-proline

Dmitrieva, Olga A. ; Fedotova, Marina V. ; Buchner, Richard



Abstract

In nature the amino acid L-proline (Pro) is a ubiquitous and highly effective osmolyte protecting cells against osmotic stress. To understand this effect knowledge of the hydration of Pro and its interactions with dissolved salts is essential. We studied these properties by combining statistical mechanics and broadband dielectric spectroscopy and found that Pro remains strongly hydrated up to ...

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