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Photoluminescence of Cu(I)(PPh 3 ) 2 (8-quinolinolate)

Vogler, Arnd


The complex Cu(I)(PPh3)(2)(oxinate) with oxine = 8-quinolinole is luminescent under ambient conditions. In the solid state it shows an emission which originates from the lowest-energy oxinate ILCT state. It consists of a fluorescence and a phosphorescence. In solution saturated with argon, a single broad emission band appears which seems to be composed of a more intense fluorescence and a much ...


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