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Iron-Catalyzed Cyclotrimerization of Terminal Alkynes by Dual Catalyst Activation in the Absence of Reductants

Brenna, Davide, Villa, Matteo, Gieshoff, Tim N., Fischer, Fabian, Hapke, Marko and Jacobi von Wangelin, Axel (2017) Iron-Catalyzed Cyclotrimerization of Terminal Alkynes by Dual Catalyst Activation in the Absence of Reductants. Angewandte Chemie International Edition 56 (29), pp. 8451-8454.

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Other URL: http://doi.org/10.1002/anie.201705087


Abstract

Catalyzing C-C bond-forming reactions with earth-abundant metals under mild conditions is at the heart of sustainable synthesis. The cyclotrimerization of alkynes is a valuable atom-efficient reaction in organic synthesis that is enabled by several metal catalysts, including iron. This study reports an effective iron-catalyzed cyclotrimerization for the regioselective synthesis of ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Axel Jacobi von Wangelin
Identification Number:
ValueType
10.1002/anie.201705087DOI
Keywords:2+2+2 CYCLOADDITION; INTRAMOLECULAR CYCLOTRIMERIZATION; HETEROGENEOUS CATALYSIS; ORGANIC-SYNTHESIS; COMPLEXES; DIYNES; METAL; HYDROGENATIONS; TRIYNES; alkynes; arene synthesis; cyclotrimerization; iron; nanoparticles
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39372
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