Go to content
UR Home

Visible-light photoredox-catalyzed desulfurization of thiol- and disulfide-containing amino acids and small peptides

Lee, Myungmo ; Neukirchen, Saskia ; Cabrele, Chiara ; Reiser, Oliver



Abstract

A scalable protocol for the desulfurization of cysteine by using visible light, the photocatalyst Ir(dF(CF3)ppy)(2)(dtb-bpy)PF6 and triethylphosphite under biphasic reaction conditions has been developed. The loading of the catalyst can be as low as 0.01mol%, which can be efficiently removed during the workup (0.3ppm), giving rise to the corresponding desulfurized product in high yields. This ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de
0941 943 4239

Dissertations: dissertationen@ur.de
0941 943 3904

Research data: daten@ur.de
0941 943 4239

Contact persons