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Oxidative P−P Bond Addition to Cobalt(−I): Formation of a Low-Spin Cobalt(III) Phosphanido Complex

Coburger, Peter , Demeshko, Serhiy, Rödl, Christian, Hey-Hawkins, Evamarie and Wolf, Robert (2017) Oxidative P−P Bond Addition to Cobalt(−I): Formation of a Low-Spin Cobalt(III) Phosphanido Complex. Angewandte Chemie International Edition 56 (50), pp. 15871-15875.

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Other URL: http://doi.org/10.1002/anie.201709140


Abstract

The first homoleptic cobalt phosphanido complex [K(thf)(4)][Co{1,2-(PtBu2)(2)C2B10H12}(2)] (1) was prepared by an unprecedented oxidative P-P bond addition of an ortho-carborane-substituted 1,2-diphosphetane to cobalt(-I) in [K(thf)(0.2)][Co((4)-cod)(2))] (cod=1,5-cycloctadiene). Compound 1 is a rare distorted tetrahedral 3d(6) complex with a low-spin ground state configuration. Magnetic ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf
Identification Number:
ValueType
10.1002/anie.201709140DOI
Keywords:TRANSITION-METAL; COORDINATION CHEMISTRY; KETIMIDE COMPLEX; BUILDING-BLOCK; LIGANDS; STATE; REACTIVITY; IONS; TETRAKIS(1-NORBORNYL)COBALT; 4-COORDINATE; carboranes; cobalt; density functional theory calculations; homoleptic compounds; P ligands
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39468
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