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Oxidative P−P Bond Addition to Cobalt(−I): Formation of a Low-Spin Cobalt(III) Phosphanido Complex

Coburger, Peter ; Demeshko, Serhiy ; Rödl, Christian ; Hey-Hawkins, Evamarie ; Wolf, Robert


The first homoleptic cobalt phosphanido complex [K(thf)(4)][Co{1,2-(PtBu2)(2)C2B10H12}(2)] (1) was prepared by an unprecedented oxidative P-P bond addition of an ortho-carborane-substituted 1,2-diphosphetane to cobalt(-I) in [K(thf)(0.2)][Co((4)-cod)(2))] (cod=1,5-cycloctadiene). Compound 1 is a rare distorted tetrahedral 3d(6) complex with a low-spin ground state configuration. Magnetic ...


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