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Synthesis and Characterization of [Rb([18]crown-6)]3 As15 Zn·4NH3 and [Rb([2.2.2]crypt)]4 Sb14 Zn·8NH3

Kaas, Marina and Korber, Nikolaus (2017) Synthesis and Characterization of [Rb([18]crown-6)]3 As15 Zn·4NH3 and [Rb([2.2.2]crypt)]4 Sb14 Zn·8NH3. Zeitschrift für anorganische und allgemeine Chemie 643 (21), pp. 1331-1334.

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Other URL: http://doi.org/10.1002/zaac.201700171


Abstract

The new compound [Rb([18]crown-6)](3)As15Zn center dot 4NH(3) was obtained by the reaction of Rb3As7, ZnPh2, [18] crown-6, and [2.2.2]crypt in liquid ammonia. The black monoclinic crystals contain the (As15Zn)(3-) anion, in which two As-7(3-) cages are linked by an As-Zn unit. The anionic units are separated by cationic [Rb([18]crown-6)](+) units. The analogous reaction of Rb3Sb7, ZnPh2, ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber
Identification Number:
ValueType
10.1002/zaac.201700171DOI
Keywords:15 ZINTL IONS; REACTIVITY; CLUSTERS; ANIONS; Polyarsenide; Polyantimonide; Liquid ammonia; Crystal structure; X-ray diffraction; Electron localization function (ELF)
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39563
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