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NMR Study of Solvation Effect on the Geometry of Proton-Bound Homodimers of Increasing Size

Gurinov, Andrei A. ; Denisov, Gleb S. ; Borissova, Alexandra O. ; Goloveshkin, Alexander S. ; Greindl, Julian ; Limbach, Hans-Heinrich ; Shenderovich, Ilya G.



Abstract

Hydrogen bond geometries in the proton-bound homodimers of quinoline and acridine derivatives in an aprotic polar solution have been experimentally studied using H-1 NMR at 120 K. The reported results show that an increase of the dielectric permittivity of the medium results in contraction of the N center dot center dot center dot N distance. The degree of contraction depends on the homodimer's ...

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