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Intraligand fluorescence of M(III)(oxinate)3 under ambient conditions with M = Fe, Ru, Os and oxinate = 8-quinolinolate

Vogler, Arnd (2017) Intraligand fluorescence of M(III)(oxinate)3 under ambient conditions with M = Fe, Ru, Os and oxinate = 8-quinolinolate. Inorganic Chemistry Communications 84, pp. 131-133.

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Other URL: http://doi.org/10.1016/j.inoche.2017.08.016


Abstract

The electronic spectra of the complexes M(III)(oxinate)(3) with M = Fe, Ru, Os and oxinate = 8-quinolinolate are dominated by oxinate to M (III) LMCT transitions. Nevertheless, these complexes are also characterized by a fluorescence at higher energies, which originates from the oxinate ligands. This green luminescence appears in solution as well as in the solid state under ambient conditions. ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie
Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1016/j.inoche.2017.08.016DOI
Keywords:COMPLEXES; PHOTOLUMINESCENCE; LUMINESCENCE; Fluorescence; Iron(III); Ruthenium(Ill); Osmium(III); 8-Quinolinolate; Intraligand excited states; Ligand to metal CT states
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39716
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