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Intraligand fluorescence of M(III)(oxinate)3 under ambient conditions with M = Fe, Ru, Os and oxinate = 8-quinolinolate

Vogler, Arnd


The electronic spectra of the complexes M(III)(oxinate)(3) with M = Fe, Ru, Os and oxinate = 8-quinolinolate are dominated by oxinate to M (III) LMCT transitions. Nevertheless, these complexes are also characterized by a fluorescence at higher energies, which originates from the oxinate ligands. This green luminescence appears in solution as well as in the solid state under ambient conditions. ...


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