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Brønsted Acid Catalysis – The Effect of 3,3’-Substituents on the Structural Space and the Stabilization of Imine/Phosphoric Acid Complexes

Melikian, Maxime, Gramueller, Johannes, Hioe, Johnny, Greindl, Julian and Gschwind, Ruth Maria (2019) Brønsted Acid Catalysis – The Effect of 3,3’-Substituents on the Structural Space and the Stabilization of Imine/Phosphoric Acid Complexes. Chemical Science 10, pp. 5226-5234.

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Date of publication of this fulltext: 26 Apr 2019 07:16

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Other URL: http://doi.org/10.1039/C9SC01044K


Abstract

BINOL derived chiral phosphoric acids (CPAs) are widely known for their high selectivity. Numerous 3,3’ substituents are used for a variety of stereoselective reactions and theoretical models of their effects are provided. However, experimental data about the structural space of CPA complexes in solution is extremely rare and so far restricted to NMR investigations of binary TRIP/imine complexes ...

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Item type:Article
Date:2019
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1039/C9SC01044KDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:40094
Owner only: item control page

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