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Controllable Isomerization of Alkenes by Dual Visible-Light-Cobalt Catalysis

Meng, Qing-Yuan , Schirmer, Tobias, Katou, Kousuke and König, Burkhard (2019) Controllable Isomerization of Alkenes by Dual Visible-Light-Cobalt Catalysis. Angewandte Chemie International Edition 131, pp. 5779-5784.

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Other URL: https://onlinelibrary.wiley.com/doi/full/10.1002/ange.201900849


We report herein that thermodynamic and kinetic isomerization of alkenes can be accomplished by the combination of visible light with Co catalysis. Utilizing Xantphos as the ligand, the most stable isomers are obtained, while isomerizing terminal alkenes over one position can be selectively controlled by using DPEphos as the ligand. The presence of the donor–acceptor dye 4CzIPN accelerates the ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse, DFG 1537/18-1, ERC No. 741623
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Keywords:alkene isomerization · cobalt · photosynthesis · visible light catalysis
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:40103
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