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Visible-Light Induced Regioselective Cycloaddition of Benzoyl Azides and Alkenes to Oxazolines

Bellotti, Peter , Brocus, Julien, El Orf, Fatima, Selkti, Mohamed, König, Burkhard , Belmont, Philippe and Brachet, Etienne (2019) Visible-Light Induced Regioselective Cycloaddition of Benzoyl Azides and Alkenes to Oxazolines. The Journal of Organic Chemistry 84, pp. 6278-6285.

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Abstract

Visible light catalysis allows the regioselective synthesis of oxazolines in high yields. The mild photosensitized manifold leverages the intermolecular formation of oxazolines with a wide functional group tolerance on both benzoyl azides and alkenes partners. Mechanistic investigations suggest the sensitization of the azide moiety as the key activation step.


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Item type:Article
Date:2019
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:Elitenetzwerk Bayern Syncat
Identification Number:
ValueType
10.1021/acs.joc.9b00568DOI
Keywords:Photocatalysis; Regioselective Cycloaddition
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:40155
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