Visible-Light Induced Regioselective Cycloaddition of Benzoyl Azides and Alkenes to Oxazolines

Zusammenfassung

Visible light catalysis allows the regioselective synthesis of oxazolines in high yields. The mild photosensitized manifold leverages the intermolecular formation of oxazolines with a wide functional group tolerance on both benzoyl azides and alkenes partners. Mechanistic investigations suggest the sensitization of the azide moiety as the key activation step.