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Visible-Light Induced Regioselective Cycloaddition of Benzoyl Azides and Alkenes to Oxazolines

Bellotti, Peter ; Brocus, Julien ; El Orf, Fatima ; Selkti, Mohamed ; König, Burkhard ; Belmont, Philippe ; Brachet, Etienne


Visible light catalysis allows the regioselective synthesis of oxazolines in high yields. The mild photosensitized manifold leverages the intermolecular formation of oxazolines with a wide functional group tolerance on both benzoyl azides and alkenes partners. Mechanistic investigations suggest the sensitization of the azide moiety as the key activation step.

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