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Site-Selective, Remote sp3 C–H Carboxylation Enabled by the
Merger of Photoredox and Nickel Catalysis

Sahoo, Basudev ; Bellotti, Peter ; Juliá-Hernández, Francisco ; Meng, Qing-Yuan ; Crespi, Stefano ; König, Burkhard ; Martin, Ruben


A photoinduced carboxylation of alkyl halides with CO2 at remote sp(3) C-H sites enabled by the merger of photoredox and Ni catalysis is described. This protocol features a predictable reactivity and site selectivity that can be modulated by the ligand backbone. Preliminary studies reinforce a rationale based on a dynamic displacement of the catalyst throughout the alkyl side chain.

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