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Site-Selective, Remote sp3 C–H Carboxylation Enabled by the
Merger of Photoredox and Nickel Catalysis

Sahoo, Basudev, Bellotti, Peter, Juliá-Hernández, Francisco, Meng, Qing-Yuan , Crespi, Stefano , König, Burkhard and Martin, Ruben (2019) Site-Selective, Remote sp3 C–H Carboxylation Enabled by the
Merger of Photoredox and Nickel Catalysis.
Chemistry - A European Journal.

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Abstract

A photoinduced carboxylation of alkyl halides with CO2 at remote sp3 C-H sites enabled by the merger of photoredox and Ni catalysis is described. This protocol features a predictable reactivity and site-selectivity that can be modulated by the ligand backbone. Preliminary studies reinforce a rationale based on a dynamic displacement of the catalyst throughout the alkyl side-chain.


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Item type:Article
Date:9 May 2019
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:Elitenetzwerk Bayern Syncat, European Union´s Horizon 2020
Identification Number:
ValueType
10.1002/chem.201902095DOI
31074058PubMed ID
Keywords:Carbon dioxide; Nickel; carboxylation; chain-walking; remote activation
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:40213
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