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Self-assembly of short chain Poly-N-isopropylacrylamid (PNIPAM) induced by superchaotropic Keggin Polyoxometalates: from globules to sheets

URN to cite this document:
Buchecker, Thomas ; Schmid, Philipp ; Grillo, Isabelle ; Drechsler, Markus ; Diat, Oliver ; Pfitzner, Arno ; Bauduin, Pierre
Date of publication of this fulltext: 04 Jun 2019 12:06


We show here for the first time that short chain poly(N-isopropylacrylamide) (PNIPAM), one of the most famous thermoresponsive polymers, self-assembles in water to form (i) discrete nanometer-globules and (ii) micrometric sheets with nm-thickness upon addition of the well-known Keggin-type polyoxometalate (POM) H3PW12O40 (PW). The type of self-assembly is controlled by PW concentration: at low PW ...


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