Abstract
The choline ion (Ch(+)) is ubiquitous in nature and also its synthetic homologue, chlorocholine (ClCh(+)), is widely used. Nevertheless, surprisingly little information on the hydration and counter-ion binding of these cations can be found in the literature. In this contribution we report effective hydration numbers, determined by dielectric relaxation spectroscopy, and ion-pair association ...
Abstract
The choline ion (Ch(+)) is ubiquitous in nature and also its synthetic homologue, chlorocholine (ClCh(+)), is widely used. Nevertheless, surprisingly little information on the hydration and counter-ion binding of these cations can be found in the literature. In this contribution we report effective hydration numbers, determined by dielectric relaxation spectroscopy, and ion-pair association constants with Cl-, determined by dilute-solution conductivity measurements. In combination with RISM calculations the obtained data suggest that for Ch(+) water is bound to the hydroxy group via hydrogen bonds whereas for ClCh(+) a rather stiff clathrate-like shell around the chlorine atom seems to be formed. With Cl- both cations form contact ion pairs with association constants of only B2 to 3 M-1.
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