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Hydration and ion association of aqueous choline chloride and chlorocholine chloride

Shaukat, Saadia ; Fedotova, Marina V. ; Kruchinin, S. E. ; Bester-Rogac, M. ; Buchner, Richard


The choline ion (Ch(+)) is ubiquitous in nature and also its synthetic homologue, chlorocholine (ClCh(+)), is widely used. Nevertheless, surprisingly little information on the hydration and counter-ion binding of these cations can be found in the literature. In this contribution we report effective hydration numbers, determined by dielectric relaxation spectroscopy, and ion-pair association ...


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