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Manganese, Iron and Cobalt Catalyzed Reductive Hydrogenation and Cross-Coupling Reactions

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Reyes-Rodriguez, Efrain
Date of publication of this fulltext: 07 Jan 2020 08:01

Abstract (English)

Chapter 2 deals with the synthesis of finely dispersed cobalt nanoparticles (Co-NP) and their application in the hydrogenation of over 60 different alkenes, alkynes, imines and heteroaromatics. The protocol presented was able to hydrogenate demanding substrates (e.g. trisubstituted olefins, quinolines) under moderate reaction conditions while tolerating ester, ether, fluoride, chloride, amine, ...


Translation of the abstract (German)

Kapitel 2 behandelt die Synthese fein verteilter Cobalt Nanopartikel (Co-NP) und ihre Anwendung bei der Hydrierung über 60 verschiedener Alkene, Alkine, Imine und Heteroaromaten. Unter dem eingesetzten Protokoll war es möglich selbst anspruchsvolle Substrate (z.B. dreifach substituierte Olefine, Chinoline) unter milden Reaktionsbedingungen zu hydrieren. Diverse funktionelle Gruppen (z.B. Ester, ...


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