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Birch‐Type Photoreduction of Arenes and Heteroarenes by Sensitized Electron Transfer

URN to cite this document:
urn:nbn:de:bvb:355-epub-406280
Chatterjee, Anamitra ; König, Burkhard
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Date of publication of this fulltext: 06 Aug 2019 11:43


Abstract

The direct reduction of arenes and heteroarenes by visible light irradiation remains challenging, as the energy of a single photon is not sufficient for breaking aromatic stabilization. Herein, we show that the energy accumulation of two visible light photons allows for the dearomatization of arenes and heteroarenes. Mechanistic investigations confirm that the combination of energy transfer and ...

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