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Birch‐Type Photoreduction of Arenes and Heteroarenes by Sensitized Electron Transfer

URN to cite this document:
urn:nbn:de:bvb:355-epub-406280
DOI to cite this document:
10.5283/epub.40628
Chatterjee, Anamitra ; König, Burkhard
Date of publication of this fulltext: 06 Aug 2019 11:43

This publication is part of the DEAL contract with Wiley.


Abstract

The direct reduction of arenes and heteroarenes by visible-light irradiation remains challenging, as the energy of a single photon is not sufficient for breaking aromatic stabilization. Shown herein is that the energy accumulation of two visible-light photons allows the dearomatization of arenes and heteroarenes. Mechanistic investigations confirm that the combination of energy-transfer and ...

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