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Charge-Induced Structural Changes in a Single Molecule Investigated by Atomic Force Microscopy

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Scheuerer, Philipp ; Patera, Laerte L. ; Simbürger, Felix ; Queck, Fabian ; Swart, Ingmar ; Schuler, Bruno ; Gross, Leo ; Moll, Nikolaj ; Repp, Jascha
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Date of publication of this fulltext: 26 Aug 2019 13:01


Intramolecular structural relaxations occurring upon electron transfer are crucial in determining the rate of redox reactions. Here, we demonstrate that subangstrom structural changes occurring upon single-electron charging can be quantified by means of atomically resolved atomic force microscopy (AFM) for the case of single copper(II)phthalocyanine (CuPc) molecules deposited on an ultrathin NaCl ...


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