Facile C=O Bond Splitting of Carbon Dioxide Induced by Metal-Ligand Cooperativity in a Phosphinine Iron(0) Complex

URN to cite this document:: urn:nbn:de:bvb:355-epub-406905
DOI to cite this document:: 10.5283/epub.40690

Leitl, J. ; Marquardt, M. ; Coburger, Peter ; Scott, D. J. ; Streitferdt, Verena ; Gschwind, R. M.

; Müller, Christian ; Wolf, Robert

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Date of publication of this fulltext: 04 Sep 2019 13:20

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Abstract

New iron complexes [Cp*FeL](-) (1-sigma and 1-pi, Cp*=C5Me5) containing the chelating phosphinine ligand 2-(2 '-pyridyl)-4,6-diphenylphosphinine (L) have been prepared, and found to undergo facile reaction with CO2 under ambient conditions. The outcome of this reaction depends on the coordination mode of the versatile ligand L. Interaction of CO2 with the isomer 1-pi, in which L binds to Fe ...