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Relaxation Dispersion NMR to Reveal Fast Dynamics in Brønsted Acid Catalysis: Influence of Sterics and H-bond Strength on Conformations and Substrate Hopping

Lokesh, N. ; Hioe, J. ; Gramüller, J ; Gschwind, R. M.



Abstract

NMR provides both structural and dynamic information, which are key to connect intermediates and to understand reaction pathways. However, fast exchanging catalytic intermediates are often inaccessible by conventional NMR due its limited time resolution. Here we show the combined application of 1H off-resonance R1ρ NMR method and low tem-perature (185-175 K) to resolve intermediates exchanging on ...

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