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CO2 or SO2: Should It Stay, or Should It Go?

dos Passos Gomes, Gabriel, Wimmer, Alexander , Smith, Joel M., König, Burkhard and Alabugin, Igor V. (2019) CO2 or SO2: Should It Stay, or Should It Go? The Journal of the Organic Chemistry 84, pp. 6232-6243.

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Abstract

A broad computational analysis of carbon-centered radical formation via the loss of either CO2 or SO2 from the respective RXO2 radical precursors (X = C or S) reveals dramatic differences between these two types of dissociative processes. Whereas the C–C scission with the loss of CO2 is usually exothermic, the C–S scission with the loss of SO2 is generally endothermic. However, two factors can ...

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Item type:Article
Date:2019
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1021/acs.joc.9b00503DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:40738
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