Synthesis and crystal structure of [Cs([2.2.2]crypt)]2[Mo(CO)5]

URN to cite this document:: urn:nbn:de:bvb:355-epub-408133
DOI to cite this document:: 10.5283/epub.40813

Kaas, Marina ; Korber, Nikolaus

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Date of publication of this fulltext: 11 Oct 2019 08:47

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Abstract

Reduction of the heteroleptic metal carbonyl complex Mo(CO)3(η5-Cp)H with the metallic salt Cs5Bi4 in the presence of [2.2.2]crypt (= 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) in liquid ammonia led to single crystals of bis[(4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane)caesium] pentacarbonylmolybdate, [Cs(C18H36N2O6)]2[Mo(CO)5] or ...