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Possible Proton Conduction Mechanism in Pseudo-Protic Ionic Liquids: A Concept of Specific Proton Conduction

Watanabe, Hikari ; Umecky, Tatsuya ; Arai, Nana ; Nazet, Andreas ; Takamuku, Toshiyuki ; Harris, Kenneth ; Kameda, Yasuo ; Buchner, Richard ; Umebayashi, Yasuhiro


In previous work, we have found that the pseudo-protic ionic liq., N-methylimidazolium acetate, [C1HIm][OAc] or [Hmim][OAc], mainly consists of the elec. neutral mol. species N-methylimidazole, C1Im, and acetic acid, AcOH, even though the mixt. has significant ionic cond. This system was revisited by employing isotopic-substitution Raman spectroscopy (ISRS) and pulsed field gradient (PFG) NMR ...


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