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Direct catalytic transformation of white phosphorus into arylphosphines and phosphonium salts

Lennert, Ulrich ; Arockiam, Percia-Beatrice ; Streitferdt, Verena ; Scott, Daniel J. ; Rödl, Christian ; Gschwind, R. M. ; Wolf, Robert



Abstract

Phosphorus compounds are ubiquitous in the chemical sciences, finding applications throughout industry and academia. Of particular interest to synthetic chemists are organophosphorus compounds, which contain P–C bonds. However, state-of-the-art processes for the synthesis of these important materials rely on an inefficient, stepwise methodology involving an initial oxidation of white phosphorus ...

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