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Direct catalytic transformation of white phosphorus into arylphosphines and phosphonium salts

Lennert, Ulrich ; Arockiam, Percia-Beatrice ; Streitferdt, Verena ; Scott, Daniel J. ; Rödl, Christian ; Gschwind, R. M. ; Wolf, Robert


Phosphorus compounds are ubiquitous in the chemical sciences, finding applications throughout industry and academia. Of particular interest to synthetic chemists are organophosphorus compounds, which contain P-C bonds. However, state-of-the-art processes for the synthesis of these important materials rely on an inefficient, stepwise methodology involving an initial oxidation of white phosphorus ...


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