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Photochemical Functionalization of Helicenes

URN to cite this document:
urn:nbn:de:bvb:355-epub-413755
DOI to cite this document:
10.5283/epub.41375
Jacubec, Martin ; Ghosh, Indrajit ; Storch, Jan ; König, Burkhard
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License: Creative Commons Attribution Non-commercial 4.0
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Date of publication of this fulltext: 24 Jan 2020 09:38

This publication is part of the DEAL contract with Wiley.


Abstract

Herein, a visible-light photochemical approach for practical helicene functionalization at very mild reaction conditions is described. The photochemical reactions allow for the regiospecific and innate late-stage functionalization of helicenes and are easily executed either through the activation of C(sp(2))-Br bonds in helicenes using K2CO3 as inorganic base or direct C(sp(2))-H helicene bond ...

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