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Photochemical Functionalization of Helicenes

URN to cite this document:
urn:nbn:de:bvb:355-epub-413755
Jacubec, Martin ; Ghosh, Indrajit ; Storch, Jan ; König, Burkhard
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Date of publication of this fulltext: 24 Jan 2020 09:38


Abstract

Herein, a visible-light photochemical approach for practical helicene functionalization at very mild reaction conditions is described. The photochemical reactions allow for the regiospecific and innate late-stage functionalization of helicenes and are easily executed either through the activation of C(sp²)-Br bonds in helicenes using K₂CO₃ as inorganic base or direct C(sp²)-H helicene bond ...

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