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Photochemical Functionalization of Helicenes

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Jacubec, Martin ; Ghosh, Indrajit ; Storch, Jan ; König, Burkhard
License: Creative Commons Attribution Non-commercial 4.0
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Date of publication of this fulltext: 24 Jan 2020 09:38


Herein, a visible-light photochemical approach for practical helicene functionalization at very mild reaction conditions is described. The photochemical reactions allow for the regiospecific and innate late-stage functionalization of helicenes and are easily executed either through the activation of C(sp(2))-Br bonds in helicenes using K2CO3 as inorganic base or direct C(sp(2))-H helicene bond ...


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