Photo-Ni dual catalytic C(sp2)–C(sp3) Cross-Coupling Reactions with Mesoporous Graphitic -Carbon Nitride as Heterogenous Organic Semiconductor Photocatalyst

URN to cite this document:: urn:nbn:de:bvb:355-epub-416356
DOI to cite this document:: 10.5283/epub.41635

Khamrai, Jagadish

; Ghosh, Indrajit

; Savateev, Aleksandr ; Antonietti, Markus

; König, Burkhard

Preview

PDF
(1MB)

Date of publication of this fulltext: 18 Feb 2020 12:12

Alternative links to fulltext:DOI Publisher

Details

Preview

Indexed in

Export bibliographical data

Abstract

The synergistic combination of a heterogeneous organic semiconductor mesoporous graphitic carbon nitride (mpg-CN) and a homogeneous nickel catalyst with visible-light irradiation at room temperature affords the C(sp(2))-C(sp(3)) cross-coupling of aryl halides and potassium alkyl trifluoroborates by single electron transmetallation. Like the homogeneously catalyzed protocol, the reaction is ...