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Photo-Ni dual catalytic C(sp2)–C(sp3) Cross-Coupling Reactions with Mesoporous Graphitic -Carbon Nitride as Heterogenous Organic Semiconductor Photocatalyst

URN to cite this document:
urn:nbn:de:bvb:355-epub-416356
DOI to cite this document:
10.5283/epub.41635
Khamrai, Jagadish ; Ghosh, Indrajit ; Savateev, Aleksandr ; Antonietti, Markus ; König, Burkhard
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Date of publication of this fulltext: 18 Feb 2020 12:12


Abstract

The synergistic combination of a heterogeneous organic semiconductor mesoporous graphitic carbon nitride (mpg-CN) and a homogeneous nickel catalyst with visible-light irradiation at room temperature affords the C(sp(2))-C(sp(3)) cross-coupling of aryl halides and potassium alkyl trifluoroborates by single electron transmetallation. Like the homogeneously catalyzed protocol, the reaction is ...

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