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Photo-Ni dual catalytic C(sp2)–C(sp3) Cross-Coupling Reactions with Mesoporous Graphitic -Carbon Nitride as Heterogenous Organic Semiconductor Photocatalyst

URN to cite this document:
urn:nbn:de:bvb:355-epub-416356
Khamrai, Jagadish ; Ghosh, Indrajit ; Savateev, Aleksandr ; Antonietti, Markus ; König, Burkhard
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Date of publication of this fulltext: 18 Feb 2020 12:12


Abstract

The synergistic combination of a heterogeneous organic semiconductor mesoporous graphitic carbon nitride (mpg-CN) and a homogeneous nickel catalyst with visible light irradiation at room temperature affords the C(sp2)‒C(sp3) cross coupling of aryl halides and potassium alkyl trifluoroborates by single electron transmetallation. Like the homogeneously catalysed protocol, the reaction is compatible ...

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