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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-416987
- DOI to cite this document:
- 10.5283/epub.41698
This publication is part of the DEAL contract with Wiley.
Abstract
The chemistry of polyphosphorus cations has rapidly developed in recent years, but their coordination behavior has remained mostly unexplored. Herein, we describe the reactivity of [P5R2]+ cations with cyclopentadienyl metal complexes. The reaction of [CpArFe(μ‐Br)]2 (CpAr=C5(C6H4‐4‐Et)5) with [P5R2][GaCl4] (R=iPr and 2,4,6‐Me3C6H2 (Mes)) afforded bicyclo[1.1.0]pentaphosphanes (1‐R, R=iPr and ...
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