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Functionalization of Pentaphosphorus Cations via Complexation

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Adhikari, Anup-Kumar ; Ziegler, Christoph ; Schwedtmann, K. ; Wolf, Robert
License: Creative Commons Attribution Non-commercial 4.0
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Date of publication of this fulltext: 26 Feb 2020 14:22

This publication is part of the DEAL contract with Wiley.


The chemistry of polyphosphorus cations has rapidly developed in recent years, but their coordination behavior has remained mostly unexplored. Herein, we describe the reactivity of [P5R2]+ cations with cyclopentadienyl metal complexes. The reaction of [CpArFe(μ‐Br)]2 (CpAr=C5(C6H4‐4‐Et)5) with [P5R2][GaCl4] (R=iPr and 2,4,6‐Me3C6H2 (Mes)) afforded bicyclo[1.1.0]pentaphosphanes (1‐R, R=iPr and ...


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