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Synthesis of a polyisobutylene-tagged fac-Ir(ppy)3 complex and its application as recyclable visible-light photocatalyst in a continuous flow process

Rackl, Daniel ; Kreitmeier, Peter ; Reiser, Oliver


The facile synthesis and application of a polyisobutylene-polymer-tagged, iridium(III) photocatalyst is described. The catalytic performance of this complex remains consistently high, while the installed tether allows for its convenient separation from reaction products through a thermomorphic solvent system. Excellent recycling properties were observed both in batch and in flow reactions, and ...


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