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Nickel(II) complexes as triplet emitters? IL phosphorescence of Ni(II)(binap)Cl 2 under ambient conditions

Vogler, Arnd



Abstract

The complexes M(II)(binap)Cl-2 with M = Ni and Pd and binap = 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl show an IL phosphorescence in the solid state under ambient conditions. The nickel(II) complex is a unique example of a triplet emitter. Generally, any triplet emission of Ni(II) complexes is quenched by non-emissive low-energy LF excited states. In the case of the binap complex, the LF ...

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