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Spin-State Switching of Manganese Porphyrin by Conformational Modification

Ghosh, Dibyajyoti ; Parida, Prakash ; Pati, Swapan K.



Abstract

Controlled spin-state switching in small molecules is of great interest for recent molecular spintronic and spin-caloritronic applications. The 3d transition metal incorporated porphyrin molecules with stable paramagnetic states are one of the most explored classes of molecules for this purpose where adsorption and desorption of small gaseous molecules (e.g., CO, NO, O-2) on the transition metal ...

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