Direkt zum Inhalt

Metal-free C–H sulfonamidation of pyrroles by visible light photoredox catalysis

Meyer, Andreas Uwe ; Berger, Anna Lucia ; König, Burkhard



Abstract

We report a one-step procedure for the preparation of N-(2-pyrrole)-sulfonamides from sulfonamides and pyrroles. The reaction uses visible light, an acridinium dye as photocatalyst and oxygen as the terminal oxidant for the oxidative C-N bond formation; structures of several reaction products were confirmed by X-ray structure analysis. The reaction is selective for pyrroles, due to the available ...

plus


Owner only: item control page
nach oben