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Phosphorescent iron complexes? Intraligand luminescence of solid Fe(II)(binap)Cl2 at room temperature

Vogler, Arnd


The complex Fe(II)(binap)Cl-2 with binap = 2,2,-bis(diphenylphosphino)-1,1'-binaphtyl shows an intraligand phosphorescence in the solid state under ambient conditions. Surprisingly, low-energy LF (ligand field) excited states do not quench this emission. Tetrahedral Fe(II) complexes are d(6) high-spin complexes with a quintet ground state and a quintet state as the only LF excited state. However, ...


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