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Synthesis and Application of Magnetic Noyori-Type Ruthenium Catalysts for Asymmetric Transfer Hydrogenation Reactions in Water

Eichenseer, Corina M. ; Kastl, Benjamin ; Pericàs, Miquel A. ; Hanson, Paul R. ; Reiser, Oliver


A Noyori-type ruthenium catalyst was immobilized on magnetic platforms consisting of carbon-coated cobalt nanoparticles and different polymers. Both reactivity and enantioselectivity of these catalysts were benchmarked in the asymmetric transfer hydrogenation of acetophenone in an aqueous medium. The best catalyst, having connected the ruthenium catalyst to the nanoparticle by a poly(styrene) ...


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