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{[CuSn5Sb3]2−}2: A Dimer of Inhomogeneous Superatoms

Wilson, Robert J. ; Broeckaert, Lies ; Spitzer, Fabian ; Weigend, Florian ; Dehnen, Stefanie


Reaction of the binary Zintl anion (Sn2Sb2)(2-) with the beta-diketiminato complex [LCu(NCMe)] (L= nacnac= [(N((C6H3Pr2)-Pr-i-2,6)C(Me))(2)CH](-)) in ethylenediamine or DMF affords the ternary cluster dimer {[CuSn5Sb3](2-)}(2) (1) as its [K(crypt-222)](+) salt. The chemical formulation of 1 is supported by energy-dispersive X-ray spectroscopy (EDX) and quantum chemical calculations. Each ...


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