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Reaction of Phenyl Iso(thio)cyanate with N-Heterocyclic Carbene-Supported Nickel Complexes: Formation of Nickelacycles

Pelties, Stefan ; Wolf, Robert



Abstract

The nickel(I) complex [(eta(5)-Cp)Ni(IPr)] (Cp = cyclopentadienyl, IPr = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) reacts with phenyl isothiocyanate to afford the new heteronickelacycle [(IPr)NiSC(NPh)N(Ph)CS] (1), which contains the novel bidentate and dianionic ligand {SC(NPh)N(Ph)CS}(2-). Complex 1 is also obtained from the nickel(0) compound [(IPr)-Ni(styrene)(2)] with two ...

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